不同硫组分在菱锌矿表面吸附的计算研究

采用量子化学计算的第一性原理模拟了不同硫组分在菱锌矿(001)解离面上的吸附,研究了硫组分在菱锌矿表面的吸附机理。吸附能计算结果显示:相比HS-,S2-在菱锌矿(001)解离面的吸附更加稳定,吸附能的绝对值更大,同时发现硫组分主要吸附在Zn位上;吸附前后的态密度对比分析表明,硫组分在菱锌矿表面的吸附形成了新的Zn—S化学键;布居分析发现:硫组分吸附在菱锌矿表面新形成Zn—S键的过程中,Zn、S之间发生了明显的电荷转移。研究结果阐释了菱锌矿的硫化机理,为菱锌矿硫化浮选研究提供了理论依据。     

Self-consistent kinetic theory with nonlinear wave-particle resonances

We have developed, based on the oscillating-center transformation, a general theoretical approach for self-consistent plasma dynamics including, explicitly, effects of nonlinear(higherorder) wave-particle resonances. A specific example is then given for low-frequency responses of trapped particles in axisymmetric tokamaks. Possible applications to transport as well as nonlinear wave growth/damping are also briefly discussed.     

芽孢杆菌Bacillus sp.dwc-2对模拟地下水中U(Ⅵ)的还原行为研究

在厌氧条件下研究了西南地区一种典型土壤微生物芽孢杆菌Bacillus sp.dwc-2对模拟地下水中U(Ⅵ)的还原行为，重点考察了时间、无机阴离子、腐殖酸（HA）及富里酸（FA）对还原的影响，并利用TEM、EDS、SAED和XPS对还原后的样品进行了表征。结果表明：在pH=7.0、c_NaHCO3=5 mmol/L和T=303 K条件下，Bacillus sp.dwc-2对U(Ⅵ)的还原率随时间的增加而增加，24 h内最大还原率为12.2%，此后则随时间的增加逐渐降低；HA和FA对U(Ⅵ)的微生物还原行为有一定影响，其中HA和FA浓度为25 mg/L时，U(Ⅵ)的还原在24 h最明显，其还原率分别为14.2%和16.2%，但随着HA和FA浓度的继续增加，因在U(Ⅵ)离子与HA、FA形成的配合物表面形成致密的腐殖层，抑制了电子的转移，阻止了U(Ⅵ)的还原。此外，研究表明HCO₃^-也会抑制U(Ⅵ)的还原。TEM-SAED和XPS分析证实了还原过程中U(Ⅳ)的存在。上述结果可为真实环境中微生物还原U(Ⅵ)提供基础数据和参考。     

退火温度对6.5%Si极薄带织构及磁性能的影响

采用单辊甩带法制备了厚度为0.03 mm的6.5%Si极薄带,并在真空炉中进行了880 ℃和920 ℃的退火处理。利用XRD和EBSD研究了其在退火后的宏观和微观织构演变规律。结果表明:经单辊甩带制得的6.5%Si极薄带织构主要由{001}<100>立方织构、{110}<001> Goss织构和{112}<111>织构组成。随着退火温度的升高,λ纤维仍占主导地位,且晶粒尺寸逐渐增大。特别是在920 ℃退火时,{001}<120>和{001}<100>晶粒的尺寸优势逐渐增大,不利织构{111}<110>和{111}<112>逐渐减弱,且最终的磁感应强度B₅₀=1.644 T,铁损耗P_10/400=5.896 W/kg。     

纸基底印刷无芯片RFID湿度传感器* .txt

摘要：提出了一种基于纸基底的喷墨印刷无芯片RFID湿度传感器，通过遗传算法与射频仿真软件HFSS相结合，对常规开口环谐振器结构进行分布式加载，得到目标频率为245 GHz的谐振特性良好的传感器模型；采用DMP3000型材料打印机，在不同纸基底上喷墨印刷银墨水制作传感器，以纸张本身的吸水性实现湿度传感；研究不同纸基底对湿度传感器感湿灵敏度和恢复度的影响。结果表明，柯达相纸传感器的灵敏度最高，高湿灵敏度可达到8 MHz%RH，双铜纸湿度传感器恢复度高且恢复时间短，仅为2 min；两种基底湿度传感器皆有较好的一致性、中长期稳定性，且湿敏特性在20℃～30℃范围内受温度影响较小。对纸基湿度传感器的感湿机理进行了分析，纸主要成分纤维素表面的羟基与吸附的水分子作用形成氢键，改变了基底的介电参数，传感器的湿敏特性与纸的成分和结构有关。 .txt     

某铜矿重介质产品提铁降硫选矿试验

某铜矿重介质产品铁品位56.24%，硫含量高达9.34%，95.72%的硫以磁黄铁矿的形式存在。为获得硫含量<2%的铁精矿，按磨矿—弱磁选—浮选原则流程对该矿石进行了选矿试验。试验结果表明，在最佳试验参数下，重介质产品经一段磨矿（-0.043 mm 85%）—1粗1精弱磁选—1粗2扫脱硫浮选流程处理，可获得产率45.23%、硫含量为1.52%、全铁品位66.50%的铁精矿，可作为后续钢铁冶炼原料的配矿使用，为此类重介质产品的利用提供技术参考。     

Gel-casting of transparent magnesium aluminate spinel ceramics fabricated by spark plasma sintering (SPS)

In this paper, a transparent magnesium aluminate spinel ceramic was fabricated through the newest colloidal gel casting method, using a synthetic powder with the average particle size of 90 nm and Isobutylene-Maleic Anhydride (ISOBAM) additive. ISOBAM served as both a dispersant and a gelation agent to achieve a dense body. Also, the suspension rheological behavior was optimized by the solid loading of 85 wt%, the additive content of 0.7 wt%, and the gelation time of 350 s. This led to a green body with a density equal to 65% of theoretical density and the green strength of 14.48 MPa. The results revealed that the reduction of porosity and the uniform distribution of pores in the green body (smaller than half of the initial powder particle size, 35 nm), as accompanied by spark plasma sintering (SPS), resulted in the final body density of 99.97%, as well as the high in-line transmittance of 86.7% at the wavelength of 1100 nm.     

Loadbearing capacity of infill masonry walls considering the deformation‐based membrane effect

According to currently valid codes, it is not possible to determine the loadbearing capacity of unreinforced infill walls considering the deformation‐based membrane effect by incorporating the exact support conditions. One reason for this is the lack of a validated calculation procedure, which in addition to the equilibrium conditions also realistically represents the compatibility conditions of these systems. In the present paper, therefore, a new non‐linear analytical calculation procedure is presented. The main focus of the analysis of walls subject to area loading is the incorporation of the support conditions and thus the consideration of the deformation‐based membrane compressive force. Through generalised formulation and a standardised notation of the determination equations, different material behaviours and various support conditions can be taken into account with few parameters. On the action side, both lighter loading like wind loads and heavier loading like explosion loads can be considered. Through the implementation of the partial factor concept, it is possible to comply with the requirements of European codes and thus ensure the applicability of the analysis model.